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15.3.3.2 Acknowledgment Issue. When an immediate acknowledgment (ACK) is required for a successful data transmission, the scheme presented in Section 15.3.3.1 may fail. For example, in Fig. 15.4 nodes 17 and 21 both own time slot 4, and they are allowed to transmit data simultaneously. Since they are three hops away, data packets from these two nodes will not collide with each other. The corresponding ACK packets, although transmitted from two neighboring nodes, will not collide with each other either, as an ACK packet will not be able to reach the destination of another ACK packet. The only problem is the collision between a data packet and an ACK packet. In principle, the problem can be solved by making data transmission and ACK transmission nonoverlapping (not necessary in time). This is not a problem for a new MAC protocol. However, for an existing MAC protocol, it could be dif cult to nd a satisfactory solution for the problem without modifying the MAC protocol. Most MAC schemes do not allow the ACK to be delayed, that is, the ACK should be sent within a certain short period after a data packet is received. This makes it impossible to transmit the data and its corresponding ACK in separate time slots. If not using different frequency channels or different spreading codes (as in code division multiple access) for the data transmission and the corresponding ACK transmission (Fig 15.5), then we may have to choose one of the following two solutions. One is to assign distinct time slots within three-hop neighbors instead of two-hop neighbors. The other is to separate a

The depletion of chlorine relative to sodium is a tracer for the perturbation of the background composition of sea-salt aerosols. Background aerosol shows no de cit in Cl, whereas polluted or aged aerosol reveals substantial de cits in Cl compared to seawater values [31]. Dechlorination is mainly driven by acid displacement. Particulate bromine has been measured in most regions of the MBL, and the total annual emission ux from the surface ocean has been estimated to be 6.2 Tg a 1 [31]. In this comprehensive review of inorganic bromine in the MBL, Sander et al. [31] present evidence that Br is depleted in supermicrometre sea-salt particles, while enriched in submicrometre particles. The reason for this is not yet clear and requires further study. However, such enrichments of submicrometre particles are practically absent in the remote MBL. No general latitudinal dependence of Br enrichment has been found outside the Arctic. Seasonal trends of Br enrichment with a winter maximum and a summer minimum were observed in unpolluted regions of the southern hemisphere. Bromine depletion is strongly correlated with MSA, and in high southern latitudes the loss of Br to the gas phase is a natural process [52]. Iodine in its oxidised form (IO) has been observed in coastal environments to nucleate, leading to new ultra ne particles [53]. Such iodine-containing vapours are the photolysis products of reactants emitted by marine algae. The reaction is therefore more important during daylight hours. The role of iodine in new particle production has been discussed in detail by Saiz-Lopez et al. [54]

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TCP s performance, the interplay between reliability and congestion control is not desirable and will negatively influence TCP s performance. However, in a newly designed transport protocol that does not need to conform to TCP s design, such anomalies (at least those that show up when operating over wireless networks) can be removed. Furthermore, since there are no intermediaries as in the case of the previous classes of approaches, there is no chance for the schemes of the end-to-end protocol to interfere with the schemes used by the intermediary. Approaches that belong to this category of approaches have the following characteristics: (i) retention of the end-to-end semantics of TCP; (ii) sophisticated and thoroughly customized congestion control and reliability schemes; and (iii) possibility of a comprehensive solution that addresses most of the problems identified in the previous sections. WTCP [17] is a transport protocol that belongs to this category; we elaborate on it below. 13.4.3.1 The WTCP Protocol The WTCP protocol is an end-to-end approach to improve transport layer performance over wireless networks. Although the flow control and connection management in WTCP are similar to those in TCP, WTCP uses unique mechanisms for its congestion control and reliability schemes that in tandem enable WTCP to comprehensively overcome the char-

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