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to replace f by f f0, where f0 is the number of radicals produced per light photon absorbed and f is the previously de ned initiator ef ciency. Also, quantum yields can be de ned in terms of the quantum yield for reaction of the initiator species or quantum yield for monomer polymerized. These quantum yields are not synonymous with the quantum yield for initiation.) An expression for the polymerization rate is obtained by combining Eqs. 3-50 and 3-25 to yield

6.60 12.46 13.58 14.79

Rp kp M 1=2 fIa kt 3-51

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how to print pdf file without preview using java

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That plastic instrument housing is just waiting for all the new controls you need to add to implement all the bends you ve discovered. It s yearning for em. But you may have both problems and assets hiding right under your nose.

The absorbed light intensity Ia is obtained from a consideration of the Beer Lambert law in the form

5.36 9.03 18.16 7.14

3-52

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how to print pdf file without preview using java

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0 where I0 is the incident light intensity at the outer surface of the reaction system and Ia is the 0 intensity of absorbed light on a layer at a distance D (cm) into the reaction system. Ia is not the same as the quantity Ia in Eqs. 3-50 and 3-51. Ia is the volumetric light intensity (with 0 units of mol cm 3 s 1 or, more often, mol L 1 s 1 ). Ia and I0 are surface area intensities (with units of mol cm 2 s 1 ). [A] is the molar concentration of light-absorbing photoinitiator. a is the absorption coef cient of A and varies with wavelength and temperature. a has units of L mol 1 cm 1 . (The molar absorptivity E, formerly called the extinction coef cient, is often used instead of a. a and E are related by a E ln 10 2:3E and result from the use of the base e instead of 10, respectively, in the Beer Lambert law.) Ia and, therefore, Rp vary with depth of penetration D into the reaction system [Calvert and Pitts, 1967; Terrones and Pearlstein, 2001]. The variation of Ia with D is obtained as the 0 differential of Ia with respect to D

how to print pdf file without preview using java

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3-53

5.06 8.91 16.23 10.10

So, you ve painted your alien instrument, installed all the switches, all the pots, and all the dials and LEDs. And it looks great! You carefully line up the halves of the case, bring them together, and what Why don t they go together They don t go together because the backs of the switches, the pots, and the dials and LEDs all hit the circuit board. Bummer. To avoid this all-too-common experience, be sure to look before you leap! Try to locate all your added components at points on the case that will not interfere with potential obstructions, such as the circuit board example mentioned, when the instrument is reassembled. If you do want to mount components opposite the circuit board or anything else within the case, just be certain that there s still room. To do this, measure the depth of the components that will be present on the backside of the panel they re mounted on.

The term 103 is a conversion factor (103 mL L 1 ) that converts Ia from units of mol cm 3 s 1 to mol L 1 s 1 . Combination of Eqs. 3-51 and 3-53 yields the polymerization rate as a function of D

Rp kp M 1=2 fa A I0 103 e a A D kt 3-54

3.42 7.21 9.39 8.19

Rp is the local polymeriation rate the rate at a layer located a distance D from the surface of the reaction system. Since Rp varies with the depth of penetration into the reaction system, it is useful to calculate the layer-averaged polymerization rate Rp , the average polymerization rate for a thickness D of reaction system. Rp is obtained by integrating the local rate over the layer thickness D and dividing by D to give

Rp 2kp M 1=2 fI0 103 1 e a A D=2 a A kt D 3-55

If the backside of the mounted switch measures, say, 1 2", just tape a 1 2" stack of pennies to the spot on the inside of the case where the switch would mount (see Figure 10-1).

The light intensities delivered by light sources are usually expressed in units such as kcal s 1 , kJ s 1 , or erg s 1 , and it is necessary to convert them into the appropriate units of mol L 1 s 1 before using them in the preceding equations. This is accomplished by a

2.22 7.83 5.76 3.77

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how to print pdf file without preview using java

how to print pdf file without preview using java

javascript pdf preview image

javascript pdf preview image

how to print pdf file without preview using java

javascript pdf preview image

how to print pdf file without preview using java

how to print pdf file without preview using java

javascript pdf preview image

how to print pdf file without preview using java

how to print pdf file without preview using java

javascript pdf preview image

javascript pdf preview image